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PPKTP – Periodically poled potassium titanyl

>55 J/cm² @ 1064 nm, 10 ns, 10 Hz | 400-3500 nm

Periodically Poled Potassium Titanyl Phosphate (PPKTP) is an advanced, engineered version of the standard KTP nonlinear crystal. Through a precise poling technique, PPKTP crystals have significantly expanded their range of applications, particularly in fields such as quantum optics.

Thanks to periodic poling, PPKTP enables efficient frequency conversion via quasi-phase matching (Type 0). This capability makes it an ideal choice for high efficiency nonlinear optical processes, including spontaneous parametric down-conversion (SPDC), OPO, DFG, SFG and harmonics generation.

  • Advantages
  • Disadvantages
  • Applications
  • Does not suffer from photorefraction and features a high damage threshold.
  • Enables phase matching across the entire 400–3500 nm wavelength range.
  • High nonlinearity (>10 pm/V @ Type 1, SPDC 400->800 nm)
  • Among the best options for green or red light generation, especially when CW or low-power sources are used.
  • High Gray-Track Resistive (HGTR) materials are used for best performance.
  • High-damage-threshold coatings allow pumping with significantly higher intensities compared to other periodically poled materials.
  • IBS coatings with low absorption around 3μm.
  • Laser-grade surface with low roughness available for: plano, wedged, or convex (ROC > 5 mm).
  • Small poling periods could be reached down to 2μm.
  • PPKTP crystals with lengths of 20–30 mm may be more prone to side-surface chiping, so extra care is required.
  • During the poling process, the structure of KTP is modified, which may lead to a reduction in the material’s nonlinear coefficient.
  • High CW powers still may rise Gray-Tracking effects @ 532 nm or lower wavelenghts.
  • SPDC, nth-HG, SFG, DFG frequency conversions, including 400->800 nm, 775->1550 nm or 1064->532 nm
  • Light squeezing or spectral narrowing
  • Optical parametric amplifiers, oscillators, generators for visible spectrum to mid-infrared with tunable output

3photon offers the following PPKTP crystals:

  • Standard aperture of 1×6 mm (W×H), with lengths up to 30 mm; custom apertures available upon request
  • Laser-grade surface processing: plano, wedged, or convex (ROC > 5 mm)
  • Poling periods greater than 2μm
  • Custom-designed ovens to maintain the crystal at optimal operating temperatures
  • Coating, polishing, and mounting services available upon request to ensure optimal performance

3photon standard IBS coatings examples:

S1/S2: AR(R<0.1%) @ 1064 + AR(R<0.5%) @ 532 nm, AOI = 0 deg

S1/S2: AR(R<0.35%) @ 1600 + 800 nm, AOI = 0 deg

S1/S2: AR(R<0.35%) @ 1550+775 nm, AOI = 0 deg

S1/S2: AR (R<0.5%) @ 760-800 + AR (R<0.5%) @ 1520-1600 nm, AOI = 0 deg

S1/S2: AR (R<1%) @ 1990 + AR (R<0.65%) @ 995 + 663 nm, AOI = 0 deg

  • 3photon’s unique IBS (Ion Beam Sputtering) system enables high-precision coating of nonlinear crystals. This results in superior performance compared to e-beam coatings, while simultaneously enhancing the quality, effectiveness, laser damage threshold and reduces absorption around 3μm.
  • LIDT conditions: Wavelength: 1064 nm; Pulse duration: 10 ns;1 – on – 1
    ID#, J/cm² LID def. LID max.
    KTP 59.7 101.3
  • Custom coatings are also available upon request.

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